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Preheat the oven to 400 degrees. Place the vegetable chunks on a baking sheet or very large baking dish. Pour olive oil and balsamic vinegar over the vegetables and toss well with your hands. Spread root vegetables over the baking sheet so they aren’t crowded. Sprinkle all over with salt and pepper and the herbs. Place in the oven and roast about 45 minutes, stirring every 15 minutes so the vegetables are tender and evenly browned. Serve hot.